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Contemporary media is fully aware of the trope's absurdity.
Chloroform is a "clean" takedown for henchmen. It allows the hero to be non-lethal. In Austin Powers (1997), the trope is parodied when an entire lounge full of people is knocked out instantly—acknowledging the absurdity. xxx cloroform
Chloroform is regulated under various environmental and health protection laws. Its use and disposal are subject to regulations to minimize environmental release and human exposure. Contemporary media is fully aware of the trope's absurdity